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Chem Commun (Camb). 2013 Sep 21;49(73):8060-2 doi: 10.1039/c3cc44116d. 2013 Aug 01.

[Gd(CyPic3A)(H2O)2]-: a stable, bis(aquated) and high-relaxivity Gd(III) complex

Gale EM, Kenton N, Caravan P.

Abstract

We report the synthesis and MR relevant properties of CyPic3A, a heptadentate chelator that forms ternary Gd(III) complexes of hydration state q = 2. [Gd(CyPic3A)(H2O)2](-) affords an r1 value of 5.70 mM(-1) s(-1) at 1.41 T and 310 K and displays thermodynamic stability and kinetic inertness comparable to FDA approved MR imaging probes.

PMID: 23903523
PubMed Entry
| MGH/HST Martinos Center for Biomedical Imaging

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